Understanding the low temperature electrochemistry of magnesium-lithium hybrid ion battery in all-phenyl-complex solutions

نویسندگان

چکیده

Magnesium–lithium hybrid ion batteries have emerged as a new class of energy storage systems owing to dendrite free cycling magnesium anode and possibility practice numerous conventional lithium cathodes. In present work, we used strategy analyze the performance titanate based cathode, metal anode, all-phenyl complex (APC) electrolytes at different temperatures (25 °C, 10 0 ?10 ?20 °C). The battery exhibited excellent rate (228 mAh g?1/20 mA g?1 163 g?1/1000 g?1) with stable voltage plateaus 0.90 0.75 V, which corresponds specific 178 Wh kg?1 room temperature Experimental results revealed that APC-THF solutions strong potential suppress freezing electrolyte low boiling point THF. electrochemical testing reversible capacities 213.4, 165.5, 143.8, 133.2 78.56 25, 10, 0, ?10, respectively. Furthermore, ex-situ XRD, SEM, EIS tests were carried out understand reaction kinetics both Mg2+ Li+ ions inside cathode. We hope this work will shed light on prospective devices for use in cold environments.

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ژورنال

عنوان ژورنال: Journal of Energy Chemistry

سال: 2021

ISSN: ['2096-885X', '2095-4956']

DOI: https://doi.org/10.1016/j.jechem.2020.08.018